We engaged in the business of industrial chemical products are committed for enhancing customer satisfaction & continual improvement in our Management systems & Performance.
Product name : Sikagard-694 F(I), Component A Product code : 000000612020 Type of product : paste Recommended use of the chemical and restrictions on use Product use : Sealing system Manufacturer or supplier’s details Company : Sika India Private Ltd. Unit 501-502, B- Wing, 5th floor Lotus Corporate Park Off Western Express Highway Goregaon East Mumbai 400 063 Telephone : +9122 6270 4038 E-mail address : [email protected] Emergency telephone number : +9122 6270 4038 2.
HAZARDS IDENTIFICATION Manufacture
, Storage and Import of Hazardous Chemicals Rules 1989 Classification Not classified as hazardous according to criteria laid down in Part I of Schedule-1. GHS Classification Skin corrosion/irritation : Category 2 Serious eye damage/eye irritation : Category 2A Skin sensitisation : Category 1 Long-term (chronic) aquatic hazard : Category 2
H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. Disposal: P501 Dispose of contents/ container to an approved waste disposal plan.
5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : No hazardous combustion products are known Specific extinguishing methods : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. 6.
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Deny access to unprotected persons. Environmental precautions : Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.
9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : paste Colour : off-white Odour : odourless Odour Threshold : No data available pH : Not applicable Melting point/range / Freezing point : No data available : Not applicable Flash point : 62 °C (144 °F) Method: closed cup Evaporation rate : No data available Flammability : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : ()Not applicable Relative vapour density : No data available Density : 1.65 g/cm3 (20 °C (68 °F) ()) Solubility(ies) Water solubility : insoluble Partition coefficient: noctanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : Not applicable Viscosity, kinematic : Not applicable Explosive properties : No data available
. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : The product is chemically stable. Possibility of hazardous reactions : Stable under recommended storage conditions. Conditions to avoid : No data available Incompatible materials : No data available No decomposition if stored and applied as directed. 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Components: reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight ≤ 700): Acute oral toxicity : LD50 Oral (Rat): > 5,000 mg/kg Acute dermal toxicity : LD50 Dermal (Rabbit): > 20,000 mg/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction. Respiratory sensitisation: Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT – single exposure Not classified based on available information. STOT – repeated exposure Not classified based on available information.
ECOLOGICAL INFORMATION
Ecotoxicity Components: reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight ≤ 700): Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 1.8 mg/l Exposure time: 48 h Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects Product: Additional ecological information : Toxic to aquatic life with long lasting effects. 13.
DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. 14. TRANSPORT INFORMATION International Regulations UNRTDG UN number : UN 3082 Proper shipping name :
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
(epoxy resin) Class : 9 Packing group : III Labels : 9 IATA-DGR UN/ID No. : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (epoxy resin) Class : 9 Packing group : III Labels : Miscellaneous Dangerous Goods Packing instruction (cargo aircraft) : 964 Packing instruction (passenger aircraft) : 964 IMDG-Code UN number : UN 3082 Proper shipping name :
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resin) Class : 9 Packing group : III Labels : 9 EmS Code : F-A, S-F Marine pollutant : no Transport in bulk according to IMO instruments Not applicable for product as supplied. Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations. 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture International Chemical Weapons Convention (CWC) Schedules of Toxic Chemicals and Precursors : Not applicable 16.
